The part commes from a really big project so this is a peace of the file in a basic latex file
Code: Select all
\textbf{2-Acetamido-2-deoxy-4-\textit{O}-}\textbf{(}\textbf{2-acetamido-2-deoxy-4-\textit{O}-meth\-yl-$\beta
$-}\textbf{d}\textbf{-glu\-co\-pyr\-anosyl}\textbf{)}\textbf{-1-\textit{O}-4-methyl\-umbelli\-feryl-$\beta$-}\textsc{d}\textbf{-glu\-co\-pyr\-ano\-side (x).}
\\
To a suspension of \textbf{x} (12mg, 15.70 $\mu$mol) in MeOH (1 ml) was added
NaOMe (173 $\mu $l, 30wt{\%} in MeOH, 0.4 $\mu$mol). The reaction was
stirred under exclusion of light. When LCMS (gradient 0 to 50{\%} MeOH)
showed complete conversion to product the mixture was quenched with AcOH (5
$\mu$L, 80 $\mu$mol). The reaction was diluted with \ce{H2O} (2 ml) the
MeOH was evaporated \textit{in vacuo} and the remaining \ce{H2O} was lyophilized. Purification
by HPLC (gradient \ce{H2O}-MeOH + 0.1{\%} TFA 80-20 to 60-40)
evaporation of MeOH and lyophilizing \ce{H2O} yielded x (3.5 mg, 37{\%}) as
white fluffy solid.\textbf{$^{1}$H NMR (400 MHz, (D$_{6}$) DMSO)} $\delta $ 7.90 (d, \textit{J} = 9.0
Hz, 1H, NH), 7.75 (d, \textit{J} = 9.1 Hz, 1H, NH), 7.69 (d, \textit{J} = 8.8 Hz, 1H, CH,
4-methyl\-umbelli\-feryl), 7.03 (d, \textit{J} = 2.2 Hz, 1H, CH, 4-methyl\-umbelli\-feryl),
6.95 (dd, \textit{J} = 8.8, 2.3 Hz, 1H, CH, 4-methyl\-umbelli\-feryl), 6.26 (s, 1H, CH,
4-methyl\-umbelli\-feryl), 5.16 (dd, \textit{J} = 10.8, 7.4 Hz, 2H, H$_{1}$, OH), 4.83
(t, \textit{J} = 5.3 Hz, 1H, OH), 4.74 (d, \textit{J} = 2.1 Hz, 1H, OH), 4.68 (t, \textit{J} = 5.9 Hz,
1H, OH), 4.36 (d, \textit{J} = 8.5 Hz, 1H, H$_{\mbox{1'}\beta}$), 3.77 (d, \textit{J} = 9.6 Hz, 1H), 3.70 - 3.13 (m, 14H), 2.94 (t, \textit{J} = 9.2 Hz,
1H), 2.40 (s, 3H, CH$_{3}$, 4-methyl\-umbelli\-feryl), 1.84 (s, 3H, CH$_{3}$,
Ac), 1.80 (s, 3H, CH$_{3}$, Ac); \textbf{$^{13}$C NMR (151 MHz, (D6) DMSO)} $\delta $
169.19, 160.05, 159.90, 154.41, 153.27, 126.54, 114.31, 113.44, 103.14,
101.89, 98.20, 80.66, 79.96, 75.61, 75.06, 73.78, 72.24, 59.77, 55.65,
54.41, 22.97, 18.13.
The problem is that there should be 2 small caps d in the title of my compound but only the second one is correct. The first one is just a normal letter. And i think it is because a can not put one bracket "(" bold. See code.
Thanx for looking into it.