Hyperref (see the manual page 17), defines a command which presents two alternatives, one to put in the TeX file and another in the PDF bookmarks:
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So in your case, you might use:
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To produce an \hspace in the TeX file and nothing in the bookmarks.
Is that the best solution to your problem? Probably not, but it's hard to know how to address the spacing problem otherwise without a
minimal working example. I was struck however that you're using \addcontentsline{toc}{section} rather than \addcontentsline{toc}{subsection} given the description of the problem which follows.