I have problems with links to sections, subsections etc.: in the index, they appear coloured but are not clickable. I use two PDF readers, Sumatra to view the PDF when the LaTeX file is compiled and Foxit Reader to open the PDF in any other case. So I can exclude any problem related to the PDF viewer. I use to insert every section in this simple way:
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\section{Name of the section}
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\documentclass[12pt, a4 paper]{article}
\usepackage[italian]{babel}
\usepackage[latin1]{inputenc}
\usepackage[T1]{fontenc}
\usepackage{amsfonts}
\usepackage{amsthm}
\usepackage{amssymb}
\usepackage[top=1.0cm, left=2cm, right=2cm, bottom=1cm, includefoot]{geometry}
\usepackage{latexsym}
\usepackage[usenames]{color}
\usepackage{fancyhdr}
\usepackage{graphicx}
\usepackage{pdfsync}
\usepackage{epsfig}
\usepackage{wrapfig}
\usepackage{txfonts}
\usepackage{mhchem}
\usepackage{mathtools}
\usepackage{mathcomp}
\usepackage{slashed}
\usepackage{makeidx}
\usepackage{mathrsfs}
\usepackage{braket}
\usepackage{dsfont}
\usepackage{tocbibind}
\usepackage[colorlinks=true,linkcolor=blue,urlcolor=blue,citecolor=blue]{hyperref}