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If you look at Klemens example it does not work. Unit only definitions are not applied in the document in comparison to general command using \sisetup.
Compiled it shows different behaviour pattern for \nanosecond and \ns. It seems like I can re-define existing units and have to create new ones only. Is this correct?
Settings per unit only apply to exactly that unit command. So \nanosecond and \ns are different: if you want to cahnge how \ns behaves you will need to redefine it. The reason for this is that with compound units what 'should' happen rapidly becomes impossible to tell. So siunitx only checks for a set of options for the 'outer' unit (the one you actually type in), and not for what that then is converted to.
NEW: TikZ book now 40% off at Amazon.com for a short time.
And: Currently, Packt sells ebooks for $4.99 each if you buy 5 of their over 1000 ebooks. If you choose only a single one, $9.99. How about combining 3 LaTeX books with Python, gnuplot, mathplotlib, Matlab, ChatGPT or other AI books? Epub and PDF. Bundle (3 books, add more for higher discount): https://packt.link/MDH5p