To add to what Johannes, said, that package is for aligning terms and signs vertically, such that there's a column for each variable. That's especially good if you got several variables in each row. However, it may look a bit strange in the case of a single variable in each row when all are different. That's the case above.
As Johannes wrote, cases fits better here and is easy to write. In the current situation the terms at the left have roughly the same width. But if you got different widths, it could be good to use additional alignment. Here I change
x_5
to
x_{10}
just as a demonstration. I used the aligned environment instead.
Code: Select all
\documentclass[11pt,a4paper,openany]{report}
\usepackage{amssymb,amsmath,amsthm}
\usepackage[dutch]{babel}
\usepackage{mdframed}
\usepackage{systeme,mathtools}
\usepackage{lipsum}
\usepackage{relsize}
\newcommand\md{\ }
\renewcommand{\qedsymbol}{$\blacksquare$}
\begin{document}
\systeme{x_1=2r + s -t,x_2= r, x_3=-2s +2t, x_4=s, x_10=t}
\[\begin{cases}x_1=2r + s -t\\x_2= r\\ x_3=-2s +2t\\ x_4=s\\ x_{10}=t
\end{cases}
\]
\[
\left\{\begin{aligned}
x_1 &= 2r + s -t \\
x_2 &= r \\
x_3 &= -2s + 2t \\
x_4 &= s \\
x_{10} &= t
\end{aligned}\right.
\]
\end{document}
Stefan